MOZART

MOZART chemical mechanisms

The MOZART chemical mechanisms used in CAM-chem and WACCM (components of the Community Earth System Model) are developed, maintained and updated at NCAR, with collaborations from the community. 

A full description of the MOZART mechanism in CESM2 is described in Emmons et al., JAMES, 2020. The aerosol schemes used in CESM2, including the Secondary Organic Aerosol (SOA) Volatilty Basis Set (VBS) scheme and the Modal Aerosol Model (MAM), are described in detail in Tilmes et al., JAMES, 2019. The stratospheric chemistry is discussed further in Gettelman et al., JGR, 2019.

Current MOZART mechanisms

Naming convention: T = Troposphere; S = Stratosphere; MLT = Mesosphere and Lower Thermosphere;  MA = Middle Atmosphere 

MOZART- Description Species
T1 Comprehensive troposphere 179
T1.1 Adds NOx-dependent VBS SOA formation (default in CESM2; Jo et al., 2020)  
T1.2 Reaction rates updated to JPL19.  TS1 updated to this in CAM tag cam6_3_095.  
T2 T1 plus detailed terpene oxidation (Schwantes et al., 2020) 265
T3 T1 plus speciated higher alkanes 216
T4 Simpler tropospheric VOCs 100
TS1, T1S T1 with comprehensive stratosphere; released in CESM2 (Emmons et al., 2020) 216
TSMLT, T1MA T1 with Middle Atmosphere (stratosphere, mesosphere & lower thermosphere); used for CMIP6-WACCM 225
T4S T4 with full stratosphere, suitable for climate simulations (CESM3) 134

 

Previous MOZART mechanisms

Mechanism Description Species
MOZART-1 Original mechanism based on IMAGES (Brasseur, Hauglustaine et al., JGR, 1998) 46
MOZART-2 Expanded hydrocarbons and isoprene oxidation (Horowitz et al, JGR, 2003) 59
MOZART-3 Stratospheric chemistry with MOZART-4 troposphere (Kinnison et al., JGR, 2007) 108
MOZART-4 Addition of aromatics to MOZART-2 (Emmons et al., 2010) 83

bar chart of MOZART mechanisms

 

MOZART chemical transport model (CTM)

The MOZART CTM has not been updated since the publication of MOZART-4 (Emmons et al., 2010)., and therefore is quite out of date. The source code is freely available to the community, however it is no longer being developed or supported. The capabilities of MOZART-4, with numerous improvements, are available in CAM-chem and we recommend that it be usedCAM-chem is a component of the Community Earth System Model, so can be run as a fully coupled free-running climate model, but can also be run with specified dynamics (nudged to reanalysis meteorology) to produce results similar to the MOZART CTM. Documentation on Downloading and Running MOZART-4 Source Code